KEMIRA INC -- UNITANE RUTILE TITANIUM DIOXIDE PIGMENT,OR-620 -- -
===================== Product Identification ===================== Product ID:UNITANE RUTILE TITANIUM DIOXIDE PIGMENT,OR-620 MSDS Date:08/01/1991 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:KEMIRA INC Address:ONE KEMIRA RD City:SAVANNAH State:GA ZIP:31404 Country:US Info Phone Num:800-453-6472 Emergency Phone Num:912-236-6171 Preparer's Name:JOSEPH E. CLONTS CAGE:KEMRA === Contractor Identification === Company Name:KEMIRA INC Address:ONE KEMIRA RD Box:City:SAVANNAH State:GA ZIP:31404 Country:US Phone:800-453-6472 CAGE:KEMRA Company Name:LOMAS INTERNATIONAL Address:Box:10225 City:MACON State:GA ZIP:31297 Country:US Phone:800-453-6472 CAGE:TO436 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM DIOXIDE. MOLECULAR FORMULA: TIO*2. MOLECULAR WEIGHT: 79.9. CAS:13463-67-7 RTECS #:XR2275000 Minumum % Wt:80. Maxumum % Wt:100. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:ALUMINUM HYDROXIDE CAS:21645-51-2 RTECS #:BD0940000 Minumum % Wt:0. Maxumum % Wt:10. Ingred Name:SILICA; (SILICA, AMORPHOUS) CAS:7631-86-9 Minumum % Wt:0. Maxumum % Wt:10. OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EXPOSURE TO THIS PRODUCT FOR A SHORT DURATION IS NOT LIKELY TO CAUSE ADVERSE EFFECTS DIRECTLY AFTER EXPOSURE. CHRONIC OVEREXPOSURE TO TITANIUM DIOXIDE MAY CAUSE SLIGHT LUNG FIBROSIS. WHEN TITANIUM DIO XIDE WAS FED TO RATS AND MICE FOR THEIR LIFETIMES IN A CARCINOGEN BIOASSAY, IT WAS NOT CARCINOGENIC. HOWEVER, INHALATION OF TITANIUM DIOXIDE DUSTS AT 50 TIMES THE NUISANCE DUST LEVEL CAUSES FIBROSIS A ND A SLIGHT INCREASE IN LUNG TUMORS FOUND IN LAB RATS. Explanation of Carcinogenicity:NONE OF THE COMPONENTS OF UNITANE TITANIUM DIOXIDE IS LISTED AS A CARCINOGEN BY IARC, NTP OR OSHA. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:INHALATION: IF A LARGE AMOUNT OF DUST IS INHALED, REMOVE PERSON TO FRESH AIR. IF NOT BREATHING, ADMINISTER ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. OBTAIN MEDICAL ASSISTAN CE. EYES: IMMEDIATELY FLUSH WITH LARGE VOLUME OF WATER FOR AT LEAST 15 MINUTES. OBTAIN MEDICAL ASSISTANCE. SKIN: PIGMENT IS NOT HAZARDOUS BUT WASHING EXPOSURE AREAS AFTER USE IS RECOMMENDED. INGESTION : NO SPECIFIC ACTION IS RECOMMENDED. OBTAIN MEDICAL ASSISTANCE IF NECESSARY. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . MATERIAL WILL NOT BURN. Unusual Fire/Explosion Hazard:NFPA &/OR HMIS RATINGS: HEALTH - 0; FLAMMABILITY - 0; REACTIVITY - 0. ================== Accidental Release Measures ================== Spill Release Procedures:SHOVEL THE MATERIAL INTO AN APPROPRIATE DISPOSAL CONTAINER. WASH THE AREA WITH WATER. ====================== Handling and Storage ====================== Handling and Storage Precautions:TO INSURE THE INTEGRITY OF THE PRODUCT KEEP DRY. AVOID BREATHING DUST. USE A NIOSH APPROVED DUST FILTER RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED. Other Precautions:PERSONAL PROTECTION IS DETERMINED BY THE CONSUMER FOLLOWING INFORMATION PROVIDED IN THE EXPOSURE CONTROL INFORMATION SECTION OF THIS MSDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATORY PROTECTION IS GENERALLY NOT REQUIRED DURING NORMAL OPERATIONS. IF EXPOSUE LIMITS ARE EXCEEDED NIOSH APPROVED AIR PURIFYING RESPIRATORS WITH PARTICULATE FILTERS SHOULD BE USED. Ventilation:ENGINEERING CONTROLS ARE NOT USUALLY NECESSARY, IF GOOD HYGIENE PRACTICE'S ARE STRICTLY FOLLOWED. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Supplemental Safety and Health PHYSICAL AND CHEMICAL PROPERTIES: OCTANOL/H*2O PARTITION COEFFICIENT: NOT AVAILABLE. SATURATION IN AIR (BY VOLUME): NOT APPLICABLE. ================== Physical/Chemical Properties ================== Boiling Pt:>2500.C, 4532.F B.P. Text:4532-5432F; 2500-3000C Melt/Freeze Pt:>1830.C, ######F M.P/F.P Text:3326-3362F; 1830-1850C Spec Gravity:4.2 Solubility in Water:NOT SOLUBLE Appearance and Odor:WHITE POWDER; ODORLESS. Percent Volatiles by Volume:<2 (BY WT) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO SPECIFIC INCOMPATIBILITY. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:MATERIAL WILL NOT DECOMPOSE. =================== Toxicological Information =================== Toxicological Information:OTHER INFO: OSHA BELIEVES RISK IS NOT THREAT TO YOUR HLTH AS LONG AS EXPOS TO FIBER GLASS WOOL IS <1 FIBER/CUBIC CENTIMETER (CC) TWA (8 HR TIME WEIGHTED AVERAGE). FIBER GLASS WOOL EXPOS IN HOME, COMME RCIAL BUILDINGS, & MFG FACILITIES ARE GENERALLY FOUND TO BE WELL BELOW 1 FIBER/CC. INSTALLERS & FABRICATORS SHOULD BE AWARE OF THEIR EXPOS LEVELS & TAKE APPROP ACTIONS IF NEEDED PER REC WORK PRACTICES . KNAUF STRONGLY RECOMMENDS FOLLOWING ALL SAFE WORK PRACTICES WHILE WORKING WITH AND/OR INSTALLING FIBER GLASS WOOL PRODUCTS. ===================== Ecological Information ===================== Ecological:RESP PROT: FOR RESP PROT, NIOSH IMMED DANGEROUS TO LIFE/HLTH (IDLH) LEVEL FOR AMMONIA. UP TO 10X PEL FOR FORMALDEHYDE, & UP TO 50% VOLUNTARY PEL: NIOSH APPRVD FULL FACE RESP W/FORMALDEHYDE CARTRIDGE/C ANISTERS & DUST/MIST PREFILTERS. UP TO IDLH FOR FORMALDEHYDE: NIOSH APPRVD FULL FACE MASK W/CHIN STYE/CHEST/BACK MOUNTED TYPE INDUST SIZE CANISTER SPECIFICALLY APPRVD FOR PROT AGAINST FORMALDEHYDE. UP TO IDLH FOR AMMONIA UP TO 50% VOLUNTARY PEL: NIOSH APPRVD FULL FACE RESP W/AMMONIA CARTRIDGES & CANISTER, AND A DUST/MIST PREFILTER. ==================== Disposal Considerations ==================== Waste Disposal Methods:ANY DISPOSAL MUST BE MADE WITHIN FEDERAL, STATE AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:THE MATERIAL IS NOT REGULATED AS A HAZARDOUS MATERIAL BY THE DOT OR IMO. THE MATERIAL IS SHIPPED IN FIFTY (50) POUND PAPER BAGS AND BULK BAGS BY TRUCK AND RAIL. ===================== Regulatory Information ===================== SARA Title III Information:NOT LISTED. Federal Regulatory Information:TSCA INVENTORY: REPORTED/INCLUDED. CANADIAN WHMIS CLASSIFICATION: NOT REGULATED. CANADIAN DOMESTIC SUBSTANCE LIST (DSL): NOT LISTED. State Regulatory Information: ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.